Thermoelectric phenomena are traditionally associated with the interconversion of thermal and electrical energy in many-body systems. In the context of high-temperature quantum chromodynamics (QCD) matter produced in relativistic heavy-ion collisions, thermoelectric responses can provide insight into the evolving microscopic dynamics and the redistribution of effective degrees of freedom across the phase transition region. In this work, for the first time, we present a phenomenological study of the thermoelectric figure of merit ( ZT) in hot QCD matter, with a particular focus on its behavior across the hadronic and quark-gluon plasma phases. Using model-based calculations for the electrical conductivity, Seebeck coefficient, and thermal conductivity, we analyze the temperature dependence of ZT and identify characteristic features near the QCD phase transition temperature. Our results indicate that ZT exhibits nontrivial behavior near the transition region, reflecting the changing transport properties and active degrees of freedom in the medium. This phenomenological study of the thermoelectric figure of merit provides a complementary perspective to traditional transport studies and may provide critical insights for advancing the understanding of QCD matter through the transition region.